Last edited by Faulkree
Monday, August 3, 2020 | History

5 edition of Olefin Metathesis and Polymerization Catalysts: Synthesis, Mechanism and Utilization (NATO Science Series C:) found in the catalog.

Olefin Metathesis and Polymerization Catalysts: Synthesis, Mechanism and Utilization (NATO Science Series C:)

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  • 40 Currently reading

Published by Springer .
Written in English

    Subjects:
  • Catalysis,
  • Technology & Industrial Arts,
  • Engineering - Chemical & Biochemical,
  • Science,
  • Science/Mathematics,
  • Metathesis (Chemistry),
  • Chemistry - Organic,
  • Chemistry - Physical & Theoretical,
  • Science / Chemistry / Physical & Theoretical,
  • Science-Chemistry - Organic,
  • Science-Chemistry - Physical & Theoretical,
  • Technology / Engineering / Chemical & Biochemical,
  • Alkenes,
  • Congresses,
  • Polymerization

  • Edition Notes

    ContributionsYavuz Imamogammalu (Editor), Birgül Zümreogammalu-Karan (Editor), Allan J. Amass (Editor)
    The Physical Object
    FormatHardcover
    Number of Pages596
    ID Numbers
    Open LibraryOL7806484M
    ISBN 100792310403
    ISBN 109780792310402

    The most likely dissociative mechanism with trans olefin coordination is investigated for the metathesis reaction between the "first-" and the "second-generation" Grubbs-type catalysts 1 and (H(2. Olefin Metathesis Grubbs Reaction. Olefin Metathesis allows the exchange of substituents between different olefins - a transalkylidenation. This reaction was first used in petroleum reformation for the synthesis of higher olefins (Shell higher olefin process - SHOP), with nickel catalysts under high pressure and high temperatures.

    General Information. Ring Opening Metathesis Polymerization (ROMP), a term coined by CalTech chemist Robert Grubbs, is a variant of the olefin metathesis reaction uses strained cyclic olefins to produce stereoregular and monodisperse polymers and co-polymers. Mechanism. The mechanism of the ROMP reaction involves an alkylidene catalyst and is identical to the mechanism of olefin.   Coordination Polymerization Ethylene Polymerization Anionic Polymerization Polymerization Catalyst Olefin Polymerization These keywords were added by machine and not by the authors. This process is experimental and the keywords .

    This is a complete examination of the theory and methods of modern olefin metathesis, one of the most widely used chemical reactions in research and industry. Provides basic information for non-specialists, while also explaining the latest trends and advancements in the field to experts Discusses the various types of metathesis reactions, including CM, RCM, enyne metathesis, ROMP, and tandem.   Introduction. Olefin metathesis is a powerful method for the construction of C=C bonds in a large number of synthetic contexts, including target oriented synthesis, 1 polymer chemistry, 2 and renewable feedstock derivatization. 3 Extensive efforts have been made to design tailored catalysts for each application. 4 The development of asymmetric olefin metathesis catalysts has enabled the Cited by:


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Olefin Metathesis and Polymerization Catalysts: Synthesis, Mechanism and Utilization (NATO Science Series C:) Download PDF EPUB FB2

About this book. Olefin metathesis reaction can be considered as one of the most successful organic reactions with many applications in the low molecular weight range and also in the polymer field. The use of catalysts with their selective and effective transformation properties in olefin metathesis I polymerization systems is a growing interest.

Olefin metathesis reaction can be considered as one of the most successful organic reactions with many applications in the low molecular weight range and also in the polymer field. The use of catalysts with their selective and effective transformation properties in olefin metathesis I polymerization systems is a growing interest.

Olefin Metathesis and Metathesis Polymerization provides a broad, up-to-date account of the subject from its beginnings in to the latest applications in organic synthesis. The book follows the same format as the original, making it useful toteachers and to researchers, and will be of particular interest to those working in the fields of organic chemistry, polymer chemistry, organometallic chemistry, catalysis.

About this book. This is a complete examination of the theory and methods of modern olefin metathesis, one of the most widely used chemical reactions in research and industry.

Provides basic information for non-specialists, while also explaining the. The first NATO Advanced Study Institute on Mechanism and Utilization book Metathesis and Polymerization Catalysts was held on Septemberin Akcay, Turkey.

Based on the fundamental research of RRSchrock, RGrubbs and r in the field of ring opening metathesis polymerization (ROMP), acyclic diene metathesis (ADMET) and alkyne polymerization, these areas gained growing interest within. Mechanism and Activity of Ruthenium Olefin Metathesis Catalysts Journal of the American Chemical Society.

Sanford, Love, and Grubbs Abstract: This report details the effects of ligand variation on the mechanism and activity of ruthenium-based olefin metathesis by:   This article reviews olefin metathesis, its history, use of heterogeneous and well-defined molecular catalysts, mechanism related to organometallic chemistry and application of the reactions.

Group VI and VIII transition metal catalysts are the most common in the olefin metathesis, although several other transition metal compounds also catalyze Cited by: 4. Olefin metathesis such as ring-opening metathesis polymerization (ROMP), ring-closing (RCM) and cross metathesis (CM) reaction [1–4] have attracted considerable attention due to the promising possibility for application not only to polymer synthesis but also to synthesis of valuable organic compounds [1–4].

This volume contains the main lectures and seminars given at the NATO Advanced Study Institute on " Olefin Metathesis and Polymerization Catalysts: Synthesis, Mechanism and Utilization", held at Akcay.

Babkesir. Turkey between 10th and 22nd September Texte du rabatBook Edition: This volume contains the main lectures and seminars given at the NATO Advanced Study Institute on " Olefin Metathesis and Polymerization Catalysts: Synthesis, Mechanism and Utilization", held at Akcay.

Babkesir. Turkey between 10th and 22nd September Olefin Metathesis and Metathesis Polymerization provides a broad, up-to-date account of the subject from its beginnings in to the latest applications in organic synthesis. The book follows the same format as the original, making it useful toteachers and to researchers, and will be of particular interest to those working in the fields of.

* The standard work on one of the most fascinating reactions in synthesis * The team of authors reads like a "Who's who" of metathesis * Clearly divided into catalyst developments, organic synthesis applications and polymer synthesis * Presents the commercial applications, too.

Catalytic olefin metathesis is a powerful chemical transformation that can convert simple double-bond containing compounds into more complex chemical entities.

For this reason, it Cited by: Olefin metathesis is an organic reaction that entails the redistribution of fragments of alkenes by the scission and regeneration of carbon-carbon double bonds.

Because of the relative simplicity of olefin metathesis, it often creates fewer undesired by-products and hazardous wastes than alternative organic reactions. For their elucidation of the reaction mechanism and their discovery of a variety of highly active catalysts Organic Chemistry Portal: olefin-metathesis.

14 Ruthenium-Benzylidene Olefin Metathesis Catalysts Georgios C. Vougioukalakis 15 Ruthenium-Indenylidene and Other Alkylidene Containing Olefin Metathesis Catalysts César A.

Urbina-Blanco, Stefano Guidone, Steven P. Nolan, and Catherine S. Cazin 16 Hoveyda-Type Olefin Metathesis Complexes Yakov Ginzburg and N. Gabriel Lemcoff. This volume contains the main lectures and seminars given at the NATO Advanced Study Institute on " Olefin Metathesis and Polymerization Catalysts: Synthesis, Mechanism and Utilization", held at Price: $ ISBN: OCLC Number: Notes: "Proceedings of the NATO Advanced Study Institute on Olefin Metathesis and Polymerization Catalysts, Alcay, Turkey, September"--Title page verso.

ZN catalysts are effective for polymerization of α-Olefins (ethylene, propylene) and some dienes (butadiene, isoprene). However, they don’t work for some other monomers, such as disubstituted double bonds. Vinyl chloride cannot be polymerized by ZN catalyst either, because free radical vinyl polymerization is initiated during the.

Olefin metathesis and metathesis polymerization. Responsibility K.J. Ivin, J.C. Mol. Imprint "Olefin Metathesis and Metathesis Polymerization" provides a broad, up-to-date account of the subject from its beginnings in to the latest applications in organic synthesis.

The book follows the same format as the original, making it useful to. Get this from a library. Olefin Metathesis and Polymerization Catalysts: Synthesis, Mechanism and Utilization. [Yavuz İmamoğlu; Birgül Zümreoğlu-Karan; Allan J Amass]. Synthesis and Activity of a New Generation of Ruthenium-Based Olefin Metathesis Catalysts Coordinated with 1,3-Dimesityl-4,5-dihydroimidazolylidene Ligands § Article Oct "Handbook of Metathesis" is an unbelievable collection of articles to the topic metathesis in three volumes.

The volumes contain contributions of Richard Schrock, Amir H. Hoveyda, Siegfried Blechert, Alois Fuerstner and other pioneers, which underlines clearly the importance of this work and above all the significance of its editor Robert H.Olefin metathesis is a popular and useful the presence of certain transition-metal compounds, including various metal carbenes, olefins exchange the groups around the double bonds, resulting in several outcomes: straight swapping of groups between two acyclic olefins (cross-metathesis), closure of large rings (ring-closing metathesis), formation of dienes from cyclic and .