4 edition of Electrochromism In Nickel-based Oxides found in the catalog.
August 31, 2004
by Uppsala Universitet
Written in English
|The Physical Object|
|Number of Pages||125|
electrochromism was ﬁrst reported in [10–13]. Tung-sten oxide has a nearly cubic structure which may be simply described as an “empty-perovskite” type formed by WO6 octahedra that share corners. The empty space inside the cubes is considerable and this provides the availability of a. Enhancement of Photochromism and Electrochromism in MoO3/Au and MoO3/Pt Thin Films. The Journal of Physical Chemistry B , (11), DOI: /jpu. Toshihiro Yamase. Photo- and Electrochromism of Polyoxometalates and Related Materials.
Plasmonic Electrochromism of Metal Oxide Nanocrystals. ,,, DOI: /ch Minjung Kim, Noa Marom, N. Scott Bobbitt, James R. Chelikowsky. A first-principles study of the electronic and structural properties of Sb and F doped SnO2 nanocrystals. Abstract. Electrochromic properties of sputter-deposited nickel-based oxide films have been studied with a two-fold goal. From a practical point of view, the optical switching performance has been improved by optimizing the deposition conditions and film stoichiometry with respect to oxygen and hydrogen, and further by adding Mg, Al, Si, Zr, Nb or Ta to the films.
Summary This chapter contains sections titled: Introduction ‐ Colour in Mixed‐valence Systems Cobalt Oxide Indium Tin Oxide Iridium Oxide Molybdenum Trioxide Nickel Oxide . Non-electrode electrochromism and photo-electrochromism are summarised, with updated comprehensive reviews of electrochromic oxides (tungsten-trioxide particularly), metal co-ordination complexes and metal-cyanometallates, viologens and other organics; and more recent exotics such as fullerenes, hydrides, and conjugated electroactive polymers.
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Paul M. Monk received his PhD in the electrochemistry of novel electrochromic viologen species at Exeter University in A postdoctoral research fellow position () at the University of Aberdeen, in Scotland, was followed by lecturing positions in Physical Chemistry at Manchester Polytechnic () then Manchester Metropolitan University ().
electrochromic hydrated nickel vanadium oxide thin films upon proton intercalation and de-intercalation. In manuscript (To be suttmitted to Journal of Physical Chemistry B) E. Avendaño, A. Azens, G.A. Niklasson and C.G. Granqvist. Phase transitions of electrochromic hydrated nickel based oxide studied by galvanostatic intermittent titration.
Electrochromic multilayer coatings with nickel oxide and tungsten oxide films joined by a polymer electrolyte have several good properties, but their optical absorptance has remained undesirably high. This paper reports on electrochromism in films based on nickel oxide with a variety of additives (Mg, Al, Si, V, Zr, Nb, Ag, or Ta).Cited by: Reactive DC magnetron sputtering was used to make oxide films based on Ni, NiVNiAlNiMgand NiV Mg All of these films were capable of showing electrochromism in KOH.
The addition of Al or Mg increased the luminous transmittance significantly, while the charge capacity was by: Other advantages of mixed oxides is the possibility to widen the optical band gap in order to provide higher bleached-state transmittance in nickel-oxide-based and iridium-oxide-based films and to dilute expensive iridium oxide films without major changes of the electrochromism.Cited by: Electrochromism occurs in some oxides that can serve as mixed conductors for electrons and ions (Granqvist, ).Tungsten oxide is a particularly well-known electrochromic material whose atomic arrangement is shown in Figure This oxide consists of corner-sharing octahedral building blocks, each with a centrally positioned tungsten atom surrounded by six oxygen atoms so that the overall.
Nonstoichiometric nickel oxide films were made by reactive dc magnetron sputtering. Subsequent electrochemical treatment in KOH established electrochromism.
The material was studied by combined mechanical and optical measurements during electrochemical cycling, spectral infrared reflectance, XPS, and X-ray diffraction. Electrochromism may be defined as the phenomenon that gives rise to a reversible color change by the electrochemical insertion and extraction of electrons and ions into inorganic materials, for example, tungsten oxide (WO 3).
The difference in the transmittance between the colored (written) state and the fully bleached (unwritten) state. Reactive DC magnetron sputtering was used to grow thin films of Ni (93%)-V (7%) oxide and Ni (62%)-Al (38%) oxide. Both films showed electrochromism in KOH. The addition of Al diminished the luminous absorbance significantly, while the charge capacity was maintained.
The Al-containing films are superior to the conventional Ni oxide electrodes as regards applications requiring. Electrochromism - Fundamentals and Applications is the first in-depth treatise on the topic.
Written by leading scientists in the field, it is a state-of-the-art account of all aspects of electrochromism, presented at a level accessible to chemists, physicists, materials scientists and engineers.
Electrochromic materials are able to change their optical properties in a persistent and reversible way under the action of a voltage pulse.
This book explores electrochromism among the metal oxides, with detailed discussions of materials preparation (primarily by thin film technology), materials characterization by (electro)chemical and physical techniques, optical properties, electrochromic 5/5(1).
Electrochromism and Electrochromic Devices - by Paul Monk November The electrochromism in the nickel oxide materials arises from the reversible formation of hole states on the NiO6 units, which then impacts the Ni oxidation state through the Ni3d-O2p. based on oxides of W and Ni, as has been the case for the last two decades.
Section discusses optical and electronic properties in electrochromic oxides from a general perspective, and Section treats these properties in detail for the most widely used electrochromic material, that is, W oxide.
Electrochromism is the phenomenon where the color or opacity of a material changes when a voltage is applied. By doing so, an electrochromic smart window can block ultraviolet, visible or (near) infrared light instantaneously and on demand.
The ability to control transmittance of near infrared light can increase the energy efficiency of a building, reducing the amount of energy needed to cool. Platt coined the term ‘electrochromism’ in to indicate a colour generated via a molecular Stark effect (see page 4) in which orbital energies are shifted by an electric field.
His work follows earlier studies by Franz and Keldysh inwho applied huge electric fields to a film of solid oxide causing spectral bands to shift.
The obtained nickel oxide films exhibited anodic electrochromism, changing color from transparent to dark brown. Various techniques were used for characterization of the films as x-ray diffraction.
Electrochromic effects of transition metal oxides provide a great platform for studying lithium intercalation chemistry in solids. Herein, we report on an electronically modified nanocomposite nickel oxide (i.e., LiNiZrOx) that exhibits significantly improved electrochromic performance relative to the state-of-the-art inorganic electrochromic metal oxides in terms of charge/discharge.
Cambridge Core - Materials Science - Electrochromism and Electrochromic Devices - by Paul Monk. Non-electrode electrochromism and photo-electrochromism are summarised, with updated comprehensive reviews of electrochromic oxides (tungsten trioxide particularly), metal coordination complexes and metal cyanometallates, viologens and other organics; and more recent exotics such as fullerenes, hydrides and conjugated electroactive polymers are.
Transparent films of Cr oxide and Ni oxide were made by reactive DC magnetron sputtering in Ar+O2+H2. They displayed anodic electrochromism with charge capacities similar to that of W oxide.Electrochromism in thus stabilized films is consistent with reversible changes between Ni hydroxide and oxy-hydroxide, in accordance with the Bode reaction scheme.
An extension of this model is put forward to account for changes of NiO to Ni 2 O 3. It was demonstrated that electrochromism is associated solely with proton transfer.Electrochromic hydrated nickel oxide films were produced by reactive rf-magnetron sputtering followed by electrochemical treatment in KOH.
Spectrophotometry was used to study the modulation of luminous and solar transmittance and to assess the durability. 15N nuclear reaction analysis showed that coloration occurred upon hydrogen extraction.